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2 edition of preparation of carbocyclic and heterocyclic compounds from allene 1,3-dicarboxylic ester. found in the catalog.

preparation of carbocyclic and heterocyclic compounds from allene 1,3-dicarboxylic ester.

Eucharia Ify Onwuyali

preparation of carbocyclic and heterocyclic compounds from allene 1,3-dicarboxylic ester.

by Eucharia Ify Onwuyali

  • 219 Want to read
  • 34 Currently reading

Published by University of Salford in Salford .
Written in English


Edition Notes

PhD thesis, Chemistry.

SeriesD51844/84
ID Numbers
Open LibraryOL20309988M

A formal synthesis of (+)-α-allokainic acid and a total synthesis of (−)-α-kainic acid were carried out using a short, efficient, and highly stereoselective approach. From an alkyne precursor, a nickel-catalyzed cyclization and a palladium-catalyzed rearrangement were utilized in the synthesis of (+)-α-allokainic acid. From an allene precursor, a nickel-catalyzed cyclization was utilized. Stanford Libraries' official online search tool for books, media, journals, databases, government documents and more.

Benzyl acetate has an ester functional group (in red), an acetyl moiety (circled with dark green) and a benzyloxy moiety (circled with light orange). Other divisions can be made. In organic chemistry, functional groups are specific substituents or moieties or bonds (except double bonds) within molecules that are responsible for the characteristic chemical reactions of those molecules. Synthesis of these compounds began through coupling of readily available aldehyde (+) and enyne Treatment of a with 1g catalyst (15 mol %) in toluene at 90 °C afforded desired a in 90% yield, which was readily converted into the key triol a (3S/3R = ) after desilylation.

1,4,2-Dithiazole is a heterocyclic compound consisting of an unsaturated five-membered ring containing two carbon atoms, one nitrogen atom, and two sulfur atoms. 1,4,2-Dithiazole compounds may be formed by the reaction of nitrile sulfide with various reactive species; for instance thiocarbonyls via a 1,3-dipolar cycloaddition reaction. These. Catalyzed cyclization of α,ω-dienes: A versatile protocol for the synthesis of functionalized carbocyclic and heterocyclic compounds [18] Journal of the American Chemical Society. DOI: /ja 1: Nomura N, RajanBabu TV.


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Preparation of carbocyclic and heterocyclic compounds from allene 1,3-dicarboxylic ester by Eucharia Ify Onwuyali Download PDF EPUB FB2

Dimethyl allene-1,3-dicarboxylate (1) is an excellent substrate for heterocyclic syntheses giving products with ester side-chains capable of further allene (1) has been converted into the condensed pyridones (8)–(13) by reactions with 2-aminoazoles and azines and also into the pyridones (15) and (17) using benzamidine (14) and guanidine hydrochloride (16).Cited by: Title: Allenes as Dipolarophiles and 1,3-Dipole Precursors: Synthesis of Carbocyclic and Heterocyclic Compounds VOLUME: 13 ISSUE: 14 Author(s):Teresa M.

Pinho e Melo Affiliation:Department of Chemistry, University of Coimbra, Coimbra, Portugal. Abstract: The use of allene derivatives in the 1,3-dipolar cycloaddition either as dipolarophiles or 1,3-dipole precursors is by: A.R.

Katritzky, C.W. Rees, in Comprehensive Heterocyclic Chemistry, Carbocyclic Chemistry. Carbocyclic compounds are very usefully divided into (a) saturated (alicyclic) compounds, (b) aromatic compounds and (c) the intermediate partially unsaturated (alicyclic) compounds.

Heterocyclic compounds can be subdivided in exactly the same way, and equally usefully. Rearrangement of 4-aminonitropyrimido[4,5-b][1,5]benzothiazepine using H 2 O 2 in AcOH gave compounds () 〈83URP〉 and cyclocondensation of compound () using RCH 2 CN in the presence of KCN–DMF afforded the derivatives () (Equation (67)) 〈81H(16)〉.Reaction of 8-bromopyrido[2,3-f]quinoline with KNH 2 in liquid ammonia gave compound () and a trace of the.

L.N. Sobenina, in Advances in Heterocyclic Chemistry, Synthesis of pyrroles from ketoximes using propyne (allene) Heterocyclization of ketoximes with propyne or allene in superbase MOR–DMSO, leading to 2-alkyl(aryl, hetaryl)methyl- 53 and 2,3-dialkylmethylpyrroles 54 in yields of up to 63%, was accomplished (Equation ( Preparation.

Spiro compounds present unique preparative challenges, whether each ring contributing to its structure is unique or identical, or whether they are carbocyclic or heterocyclic—owing to the practical implications of tetra-functionalizing the central spiro atom (often with four different groups), and of the unique aspects of.

azepine, benzazepine is the preferred name. Likewise, the compounds with two benzene rings fused to the central heterocycle are carbazole, acridine, and dibenzoazepine.

History of Heterocyclic Chemistry The history of heterocyclic chemistry began in the s, in step with the development of organic chemistry. Diazo compounds are inherently unstable to acid-promoted decomposition, and it is this instability that reflects their effectiveness for metal carbene formation through transition metal catalyzed diazodecomposition.

Diazomethane is the conjugate base of the methanediazonium ion (Equation (1)), whose pK a value of 10 suggests the driving force for the high reactivity of diazomethane. 32 In. Robert M. Moriarty, O.M. Prakash, in Advances in Heterocyclic Chemistry, 2 Lactones and Spirolactones 4,6-Dioxocarboxylic acid upon treatment with HTIB, cyclizes to dioxo- δ -lactone by intramolecular participation of the carboxylic group.

Victor Von Richter's Organic Chemistry: Carbocyclic and heterocyclic series Volume 2 of Victor Von Richter's Organic Chemistry: Or, Chemistry of the Carbon Compounds, Richard Anschütz: Author: Victor von Richter: Translated by: Edgar Fahs Smith: Edition: 3: Publisher: P.

Blakiston, Original from: Harvard University: Digitized: Sep 7. In book: Chemistry of Heterocyclic Compounds: Chromenes, Chromanones, and Chromones, Vol pp - Heterocyclic syntheses with allene-1,3-dicarboxylic esters. Reviews are listed in order of appearance in the sources indicated.

In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs.

Titles are numbered serially, and these numbers are used for. Carbocyclic uracil polyoxin C (+)-2 and its α-epimer (−)-3 were synthesized in an efficient fashion from cis(N-tert-butylcarbamoyl)cyclopentenol (±) The synthesis incorporates a concise, inexpensive chemoenzymatic synthesis of enantiopure aminocyclopentenols, a Pd(0)-catalyzed substitution reaction, and a mild reduction of an α-nitro ester by TiCl3/sodium borohydride.

The literature of the subject is correspondingly vast and of the three major divisions of organic chemistry, aliphatic, carbocyclic, and heterocyclic, the last is by far the largest.

Following a brief introduction of synthesis methods, planning strategies to construct organic compounds, particularly diverse heterocyclic scaffolds, such as poly-substituted heterocyclic.

USA USA USA US A US A US A US A US A US A US A US A US A Authority US United States Prior art keywords cyclohexene dicarboximide methyl example esters Prior art date Legal status (The legal status is an assumption and is not a legal conclusion. Recently, a one-pot easy-operational route for the synthesis of diversified carbocyclic or heterocyclic benzofused frameworks was developed by Chang et al.

[56] with the functionalization of. A dicarboxylic acid is an organic compound containing two carboxyl functional groups (−COOH). The general molecular formula for dicarboxylic acids can be written as HO 2 C−R−CO 2 H, where R can be aliphatic or aromatic.

In general, dicarboxylic acids show similar chemical behavior and reactivity to monocarboxylic oxylic acids are also used in the preparation of copolymers. Allenes as building blocks in heterocyclic chemistry Teresa M.

Pinho e Melo Received: 10 September / Accepted: 11 April / Published online: 10 May Strained carbocyclic molecules have emerged in the past decades as highly useful synthetic tools [].In this class of compounds cyclopropane and cyclobutane derivatives certainly represent the most studied and versatile organic molecules [].Due to their inherent ring strain, the selective modification of their structures can be strategically used in organic synthesis [].

Heterocyclic O O NH O O O (Aromatic compounds having sweet smell (aroma), cyclic resonance and follow Huckle's rule (4n + 2 = π electrons) e.g. Benzenoid compounds: Benzene Naphthalene Biphenyl Anthracene Phenanthrene e.g.

Non-Benzenoid compounds: Azulene e.g. Heterocyclic compounds: O S NH N Furan Thiophene Pyrrole Pyridine 5. α,β-Double Electrophilic Addition of Allene-1,3-Dicarboxylic Esters for the Construction of Polysubstituted Furans by KI/ tert -Butyl Hydroperoxide (TBHP)-Promoted Oxidative Annulation.

Chemistry - A European Journal22 (27), DOI: /chemEPB1 EPA EPA EPB1 EP B1 EP B1 EP B1 EP A EP A EP A EP A EP A EP A EP B1 EP B1 EP B1 Authority EP European Patent Office Prior art keywords compound group reaction formula heterocyclic compounds Prior art date .